Saturday, 19 September 2015

The Chemistry of the Atomic Bomb (Level 4)

Level 4: Comparison between Atomic and Hydrogen Bombs

For atoms lighter than Nickel-62, the stability of the nucleus increases as atomic mass (nucleon number) increases. Hydrogen bombs derive their energy from nuclear fusion when two light atomic nuclei fuse to form a heavier, more stable nucleus. (Refer to Level 4 of Physics for more information on nuclear fusion) 

As you have learnt in level of chemistry, the nucleus of an atom contains the positively charged protons and electrically neutral neutrons. This thus makes nuclei positively charged. Extremely high temperatures are required for the positively charged nuclei to overcome their mutual repulsion and gain enough kinetic energy to fuse. Deuterium (hydrogen-2) and tritium (hydrogen-3) are isotopes of hydrogen, and carry weak positive charges due to them only having 1 positively charged proton, making it easier to overcome their mutual repulsion and fuse into helium. 


As seen from the diagram above, hydrogen bombs rely on a fission reaction to compress the fusion fuel lithium-6 deuteride of chemical formula 6Li2H. Neutrons produced in the fission reaction bombard lithium-6 deuteride to produce tritium. The deuterium and tritium then fuse to produce helium-4 which has a more stable nucleus.


Atomic Bombs
Hydrogen Bombs
Mechanism
Nuclear Fission: splitting of heavy isotopes into smaller atoms
Nuclear fusion (fusion of nuclei of lighter atoms into larger, more stable ones) caused by fission
Cost
Expensive: rare isotopes used require enrichment to obtain a supercritical mass.
Expensive: needs both fission and fusion components.
Energy needed
Less
More as a high density & high temperature environment is required for nuclear fusion
Energy produced
Less: about 20 kilotons of TNT
More: about 10 megatons of TNT






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